Outcome = what happens during a particular event
Sample space = the universe of possible outcomes.
Outcomes should be exhaustive in describing the sample space and the outcomes should be mutually exclusive.
When these conditions are met, then the sum of probabilities for all outcomes in the sample space is 1.
For example, when quantifying risk probabilities, organisms are coded as either 1) alive or 2) dead. These outcomes meet the requirements above, and the probability of an organism being in one of these states is 1.